Isomerically pure electron-deficient anthradithiophenes and their acceptor performance in polymer solar cells.
نویسندگان
چکیده
Amide functionalized anthradithiophenes (ADTs) play active acceptor roles in polymer bulk-heterojunction solar cells. The first separation of ADT isomers is reported, and the regiochemistry of the ADT has significant impact on crystal packing and solar cell performance. Cell efficiency up to 0.80%, due in large part to high open-circuit voltage (V(OC) > 1.0 V), is achieved in bulk-heterojunction solar cells comprising syn-ADT and poly(3-hexylthiophene).
منابع مشابه
بهبود چگالی جریان و افزایش کارایی سلول خورشیدی پلیمری P3HT:PCBM با استفاده از نانومیله اکسید روی
Hybrid solar cells combine organic and inorganic materials with the aim of utilizing the low cost cell production of organic photovoltaics (OPV) as well as obtaining other advantages, such as tuneable absorption spectra, from the inorganic component. Whilst hybrid solar cells have the potential to achieve high power conversion efficiencies (PCE), currently obtained efficiencies are quite low. T...
متن کاملAcid azo dyes for efficient molecular photovoltaic: study of dye-sensitized solar cells performance
In this paper we sensitized three free-metal azo days Dye 1, Dye 2 and Dye 3 based on 1,8-naphthalimide with n-propyl as the electron donor group. We used sulfonic acid and hydroxyl substituents as the electron acceptor anchoring group in synthesized dyes. The proposed dyes were sensitized from acenaphthene as the starting material by standard reactions and characterized by different techniques...
متن کاملSynthesis and Application of Two Organic Dyes for Dye-Sensitized Solar Cells
In the present study, two new organic dyes based on indigo were prepared and used as sensitizers in dye-sensitized solar cells. To this end, indoxyl was utilized as the electron donor and cyanoacrylic acid as the electron acceptor anchoring groups. These dyes together with their corresponding intermediates were purified and characterized by FTIR, 1HNMR, 13CNMR, elemental analysis and UV-Visible...
متن کاملSynthesis and Application of Two Organic Dyes Based on Indoline in Dye-Sensitized Solar Cells
In this paper we sensitized two new organic days dye 1 and dye 2 based on thioindigo with phenothiazine as the electron donor group. We used acrylic acid and cyanoacrylic acid as the electron acceptor anchoring group in dye 1 and dye 2 respectively. The proposed dyes were sensitized from phenothiazine as the starting material by standard reactions and characterized by different techniques such ...
متن کاملInvestigation of Organic Compounds as Photosensitizer for Dye Sensitized Solar Cells
Two organic compounds (SC-23=(E)-2-Cyano-3-(2,3-dimethoxyphenyl) acrylic acid and SC-25=(E)-2-Cyano-3-(2,5-dimethoxyphenyl) acrylic acid) involving methoxy groups as the electron donor and cyanoacrylic acid group as the electron acceptor have been investigated for dye sensitized solar cells. They shows a short-circuit current density (Jsc) of 2.08 and 1.81 mA cm-2, an open circuit voltage (Voc)...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 47 27 شماره
صفحات -
تاریخ انتشار 2011